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Beilstein J. Org. Chem. 2013, 9, 2781–2792, doi:10.3762/bjoc.9.313
Graphical Abstract
Scheme 1: Autoxidation of an organic substrate RH.
Scheme 2: Inhibition of autoxidation by radical-trapping antioxidants (e.g. ArOH).
Scheme 3: Relevant reactions in co-antioxidant systems.
Figure 1: Relevant structures 1–12.
Scheme 4: Model for kinetic solvent effects on the radical-trapping activity of phenolic antioxidants.
Figure 2: The O–H stretching region of representative FTIR spectra of compound 6b (10 mM) in CCl4 containing ...
Figure 3: Oxygen-uptake plots recorded during the AIBN initiated autoxidation of styrene in chlorobenzene (50...
Figure 4: Oxygen-uptake plots recorded during the AIBN initiated autoxidation of styrene in chlorobenzene (50...
Figure 5: Regeneration efficiencies (α) observed in autoxidations of styrene in chlorobenzene (50% v/v) at 30...